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Green Chemistry
in the High School

featuring curriculum

"For Teachers, By Teachers"

 

The High School level Green Chemistry lesson plans from Beyond Benign are designed to give teachers the tools to both do and teach green chemistry in their classrooms. In the lessons below teachers will find replacement labs for their core content area teaching which they can use to do green chemistry and lessons which introduce the 12 principles of green chemistry along with labs inspired by industry examples and current research which can be used to teach green chemistry.

 

What is Green Chemistry?

  • "Writing the Principles" - Use a fun lab-based simulation to introduce the 12 principles of green chemistry in an accessible way.

    Download: [doc]

  • "The Footprint of a Chemistry Teacher" – Understand the concept of chemical footprint and why every time we use potentially hazardous chemicals we are exposing ourselves to hazard.

    Download: [doc] [ppt]

  • "Environmental Impact Factor" – Understand the concept of Environmental Impact Factor, how to calculate it and how to use it in evaluation of household products and chemical processes.

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  • "Lifecycle and Sustainability Analysis" – Discover how to use a lifecycle analysis and the sustainability triangle to evaluate a product or process for ‘green’.

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Green Chemistry in Industry

  • "VBT" – Bio-inspired Polymers: Students learn about a new technology to make the manufacturing of small electronics safer. [doc]

  • "Dye-Sensitized Blackberry Solar Cell"

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  • "Essential Oil Extraction Using Liquid CO2" - Students explore ways to extract essential oils from citrus fruits and evaluate the methods used against the 12 Principles of Green Chemistry.

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  • "TAML Industry Example" - Students explore a Presidential Green Chemistry Award winning technology while looking at the difference between hard and soft water and the concept of a catalyst.

    Download: [doc] [ppt]

  • "Sea-nine 211 Industry Example" - Students perform an LD50 lab, connecting this concept to a Presidential Green Chemistry Award winning technology used as an antifoulant.

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  • "Petretec Industry Example" - Students practice molecular model building and Lewis dot structures while considering a common plastic material and a more benign Presidential Green Chemistry Award winning technology.

    Download: [doc] [ppt]

  • "Recycling Polylactic Acid" - Students learn how to take a renewable product, a PLA plastic cup, and extend its usefulness by converting the cup into a cleaning solution.

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  • "Climate Change Chemistry" - In this unit students consider the chemistry behind the concept of climate change while exploring gases and gas laws.

    Download: [doc] [ppt]

  • "Green Chemistry, Biomimicry and Intermolecular Forces" - Students explore the use of adhesives, wetability and how biomimicry is being used by chemists to invent greener alternatives.

    Download: [intro doc] [lesson doc] [ppt]

  • "Chemistry of Cosmetics" - Students look at the materials used to make common cosmetics products. They look at the molecular structure of organic compounds and whether the shape of the molecule matters to the toxicity and potential health hazards that have been associated with cosmetic ingredients.

    Download: [doc] [ppt] [Naming Molecules ppt]

  • "Synthesis of Biodiesel" - Students consider the properties of different oils used to make biodiesel and then make their own fuel.

    Download: [doc]

Green Chemistry as Invention:
Project-Based Learning Activities

 

Green Chemistry Replacement Laboratory Exercises

  • Acids, Bases and pH: Students will measure the pH using a pH meter, pH or litmus paper, and/or indicators. Categorize or Group substances based on physical properties and observe physical properties of acids and bases.

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  • Catalysts and Oxygen: This lab replaces MnO2 Manganese Dioxide catalytic reaction. To demonstrate the effect of a catalyst on a chemical. Students will explain the concept of a catalyst and reaction rates, understand how a catalyst can improve the efficiency of a process, recognize that a chemical reaction involves reactants and products which may differ from each other and recognize that the products of the reaction will be benign.

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  • Enthalpy of Combustion: Investigating the molar heat of combustion of paraffin, C25H52, compared to soy wax. Students will be able to measure the thermal heat absorbed by water, measure the heat of combustion of paraffin and soy wax and calculate the molar heat of combustion of paraffin.

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  • Equilibrium/Le Chatelier's principle: This lesson gives students an understanding of the concept of chemical equilibrium and to demonstrate Le Chatelier’s Principle.

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  • Exothermic and Endothermic: Many teachers use the calcium chloride and ammonium nitrate reaction to show exothermic and endothermic reactions. This alternative method uses a catalase, a common enzyme found in nearly all living organisms. Students will perform an exothermic reaction, an endothermic reaction and a change in enthalpy (∆H) in an endothermic reaction.

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  • Moles, Atoms and Grams oh my!: This lesson practices the concept of the mole and the calculations involved in understanding how moles are used. Not all of the materials used are totally benign but the set up is 100% reusable.

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  • Solubility: In this lesson students will qualitatively and quantitatively describe the relationship between temperature and solubility for gases and solids. Many high school labs utilize soluble ionic solids, such as nitrate or chloride salts. The disposal of these compounds will have a negative impact on an aquatic environment. Introduction of a nitrate into an ecosystem causes a spike in algal growth and a ripple effect is felt up the food chain, or in worse case scenario eutrophication can occur. By switching the solvent to sucrose, we are utilizing a natural product that is produced naturally in all ecosystems and is benign to the environment.

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  • Sublimation: This lab replaces the traditional naphthalene sublimation lab that teachers use. Students will observe sublimation (physical properties of matter) and explain the type of change that occurred.

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  • Reactions Lab: In this lesson students will observe reactions and identify the type and products produced in those reactions and to compare reactions for their toxicity and use the 12 principles of green chemistry to examine critically the use of materials in a chemistry class.

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To get these lessons, and for any questions about the content or use of these teaching materials please contact .